煤炭工程 ›› 2015, Vol. 47 ›› Issue (3): 115-118.doi: 10.11799/ce201503038

• 研究探讨 • 上一篇    下一篇

古交东曲矿煤矸石活性混合材的制备与应用

杨慧芬,张金龙,王亚运,苑修星   

  1. 北京科技大学土木与环境工程学院
  • 收稿日期:2014-07-16 修回日期:2014-08-01 出版日期:2015-03-10 发布日期:2015-03-25
  • 通讯作者: 杨慧芬 E-mail:yanghf@ustb.edu.cn

Preparation and utilization of active mixed materials using coal gangue from Dongqu mining area in Gujiao

  • Received:2014-07-16 Revised:2014-08-01 Online:2015-03-10 Published:2015-03-25

摘要: 采用煅烧-机械粉磨联合方法激发古交东曲矿煤矸石的活性,以考察该煤矸石作为活性混合材使用的可能性及效果。按照GB/T 12957-2005《用于水泥混合材的工业废渣活性试验方法》检验煅烧制度和粉磨细度对煤矸石活性指数的影响。在温度800℃煅烧2h,粉磨至比表面积622.2m2/kg的最佳条件下,煤矸石的活性指数达到101.90%,其他指标,如放射性、SO3含量、烧失量等也达到国标要求,证明煤矸石采用煅烧-粉磨方法可制备技术指标满足国标要求的活性混合材。煤矸石的活性,主要来源于粘土类矿物煅烧转变成的非晶体矿物及部分非晶体化的石英。在强度水泥中掺加煤矸石活性混合材,可增加其产量或调节其标号。掺量低于40%时,不改变水泥标号,可提高了水泥的产量。当掺量50%~60%时,提高水泥产量,但标号降低。

关键词: 关健词:煤矸石, 煅烧, 机械粉磨, 活性混合材, 掺量

Abstract: The activity of coal gangue was studied using the combination method of calcination-mechanical grinding in order to investigate the possibility and effects of coal gangue as active mixed materials. The effect of calcination system and grinding fineness on active index of coal gangue were determined according to GB/T 12957-2005“Test method for activity of industrial waste slag used as addition to cement”. Under the optimum conditions of calcination temperature of 800 ℃ for 2h and the specific surface area of 622.2m2/kg, the active index of coal gangue reached to 101.90%, and other indicators ,such as radioactivity, SO3, loss were eligible. It is proved that the active mixed materials of coal gangue, which technical indicators meet the requirements of GB/T 12957-2005, can be prepared using above combination method. The activity of coal gangue is mainly derived from the amorphous minerals transformed from clay minerals and some amorphous silica. The addition of active mixed materials from coal gangue into the cement can increase the output or adjust the mark of cement. The cement mark is not changed and the output is increased when the amount of mixed materials is below 40%. While the amount of mixed materials is between 50%~60%, the output is increased but the cement mark is lowered.

Key words: Key words: coal gangue, calcination, mechanical grinding, active mixed materials, addition amount

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